What are temperature effects on batteries?

Answer
Temperature affects battery capacity, charging behaviour and lifetime. Cold temperatures reduce available capacity, while high temperatures accelerate chemical ageing. The severity of these effects depends strongly on battery technology: lead-acid batteries are the most temperature-sensitive, lead-carbon batteries offer improved tolerance, and lithium batteries rely on internal battery management systems to manage temperature effects.

General effects of temperature on batteries

Battery capacity and temperature

Most batteries are rated at a standard temperature of 25 °C (77 °F).

  • At lower temperatures, chemical reactions slow down → available capacity decreases
  • At higher temperatures, capacity may increase slightly → but this often reduces battery lifetime

Typical reference values (lead-acid based):

  • 0 °C → ~20% capacity reduction
  • –30 °C → ~50% capacity reduction
  • 50 °C → up to ~12% higher capacity

These values vary by battery design and application.

Charging behaviour and temperature

Temperature also affects the correct charging voltage and current.

  • Lead-acid batteries (like AGM batteries) require temperature-compensated charging
  • Lithium batteries rely on a Battery Management System (BMS) to manage this automatically
  • Incorrect charging at extreme temperatures can cause:
    • accelerated ageing
    • capacity loss
    • safety issues

Internal battery temperature (thermal mass)

Battery temperature does not instantly follow ambient air temperature.

  • Large battery systems change internal temperature slowly
  • Internal variation may be limited to ~10 °C over 24 hours
  • For accurate charging control, temperature sensors should:
    • be attached to a positive terminal
    • be lightly insulated
    • reflect actual battery temperature rather than ambient air

Battery lifetime and temperature

Higher temperatures generally shorten battery life, even if capacity appears higher.

  • Low temperatures:
    • reduce usable capacity
    • slow down chemical ageing
  • High temperatures:
    • accelerate chemical degradation
    • shorten calendar and cycle life

For lead-acid batteries, lifetime typically halves for every ~8–10 °C above 25 °C.

Do temperature effects differ by battery technology?

Yes. Temperature effects vary significantly by battery type.

Temperature effects by battery technology

Battery technologyLow-temperature effectsHigh-temperature effectsCharging limitationsDesign considerations
Flooded Lead-AcidStrong capacity lossRapid lifetime reductionTemperature-compensated charging requiredMost temperature-sensitive
AGM / GelSimilar to flooded, slightly improvedAccelerated ageingTemperature compensation requiredWidely used, climate-sensitive
Lead-CarbonImproved cold performanceMore tolerant than standard lead-acidTemperature compensation requiredSuitable for partial-state-of-charge use
Lithium-ion (LFP, NMC)Moderate capacity loss during dischargeFaster calendar ageingCharging below 0 °C often restricted by BMSTemperature managed electronically

Compared to AGM batteries, lead-carbon batteries perform better at low temperatures and partial state of charge.

Unlike lead-acid batteries, lithium batteries do not use temperature-compensated charging voltages but rely on a battery management system.

Important notes for lithium batteries

Lithium-based batteries behave fundamentally differently from lead-acid:

  • Discharging at low temperatures is usually possible
  • Charging below 0 °C may be limited or disabled to prevent lithium plating
  • No classic voltage compensation is used. The BMS dynamically controls:
    • charge current
    • voltage limits
    • safety cut-offs

Special electrolyte formulations

In extreme climates, lead-acid batteries may use:

  • Stronger electrolyte for very cold regions
  • Weaker electrolyte for hot climates

This can affect voltage values and specific gravity compared to standard references.

When do temperature effects matter most?

Temperature effects are especially relevant for:

In short

  • Cold reduces available capacity
  • Heat shortens battery lifetime
  • The impact depends strongly on battery technology
  • Correct sizing, charging strategy and temperature management are essential

Not sure how temperature affects your specific application or battery type?
Our specialists can help you select and configure the right battery system for real-world conditions.

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